Already rich from their prescient investments in breakthrough companies like online search-engine leader Google, renowned venture capitalists...

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SAN FRANCISCO — Already rich from their prescient investments in breakthrough companies like online search-engine leader Google, renowned venture capitalists John Doerr and Ram Shriram think they have discovered their next gold mine.

It’s another dot-com with a zany six-letter name — Zazzle, a startup that makes customized T-shirts, posters and postage stamps.

Backed by their respective venture-capital firms, Doerr and Shriram are investing $16 million in Zazzle and joining the Palo Alto, Calif., company’s board of directors — a job both men also hold at Google.

The investment, being announced today, will provide a marketing springboard for Zazzle, which has relied almost exclusively upon word of mouth since founder Robert Beaver II and his two sons, Bobby and Jeff, launched the Web site two years ago. The company has since grown to 100 employees.

While keeping a low profile, Zazzle has built a library of 500,000 digital images, including more than 3,500 items of copyright material licensed from the Walt Disney Co.’s treasure trove of pop culture icons like Mickey Mouse and Goofy.

Zazzle’s technology has “really opened up the vault of all our character art for the first time,” said Patrick Haley, Disney’s manager of new business development for consumer products.

Here’s how Zazzle works:

Customers pick an image to be printed on a piece of merchandise, then select a phrase from a menu. The order is supposed to be completed within 24 hours.

The company so far has been making mostly T-shirts and posters. Beginning today, Zazzle will sell customized postage stamps in a partnership with mailing-equipment maker Pitney Bowes.

A sheet of 20 first-class stamps will sell for $16.99, a 130 percent markup that matches the price charges for a similar sheet of personalized postage.

The U.S. Postal Service hopes the personal touch will become popular for commemorating special events like weddings and birthdays, giving more people a reason to use “snail mail” in an era of increasing electronic communication.

It may sound like prosaic stuff, but Doerr is convinced Zazzle is onto something big.

“This will be a smash success,” he predicted.

Doerr, perhaps the best-known partner at Silicon Valley-based Kleiner Perkins Caufield & Byers, has long been one of the commercial Internet’s most outspoken zealots.

His enthusiasm has rarely wavered, even when the dot-com bust obliterated hundreds of Internet startups, taking along billions of dollars.

“That was just the tail end of the first boom,” he said. “We are no further along than the early adolescence of the Web.”

Until recently, many venture capitalists have been avoiding Internet investments, particularly those in the crowded field of e-commerce.

Though venture capitalists poured $28 billion into e-commerce startups in 1999 and 2000, the sector attracted only about $650 million in each of the last two years, according to PricewaterhouseCoopers and Thomson Financial. The pace picked up a bit during the first three months of 2005, when venture capitalists invested $181.5 million in e-commerce.

Doerr’s track record ensures that his latest bet will attract attention. He has previously hit the jackpot with early investments in Web browser pioneer Netscape Communications, online retailer and, of course, Google.

But he hasn’t matched that success with investments in, and

Google may become Doerr’s crowning achievement.

The $12.5 million he invested in 1999, when hardly anyone was interested in online search engines, turned into a Kleiner Perkins stake worth $1.8 billion by the time the company went public in 2004.

The stock has more than tripled since then, enabling Kleiner Perkins to retain a $1.7 billion stake in Google even though the firm has sold most of its shares.

Shriram, who met Doerr as one of the early executives at Netscape, got involved in Google even earlier. After leading a small group of investors that placed $1 million in the search engine in 1998, Shriram retains a stake worth $1.3 billion.

Doerr isn’t quite ready to predict the Zazzle investment will match those huge returns, but he can’t resist drawing parallels. “They are Googlesque in their energy and their ability to think big,” he said.